Limiting reactant formula
Every reactant must first be expressed in moles. Divide the available moles of each reactant by its coefficient in the balanced equation. The reactant with the smaller result has the smaller reaction extent and limits the reaction.
After finding the smallest reaction extent, calculate the theoretical amount of product:
If product mass is required, multiply the calculated product moles by its molar mass.
Calculation process
How to use the limiting reactant calculator
- Write and balance the complete chemical equation.
- Enter the name, available amount, unit, and coefficient for reactant A.
- Enter the corresponding information for reactant B.
- Supply molar masses for amounts entered in grams.
- Enter the product coefficient and choose moles or grams for the result.
- Calculate and review the limiting reactant, excess reactant, and theoretical yield.
Worked example
Hydrogen and oxygen limiting-reactant example
Consider the balanced reaction:
Suppose 2 moles of hydrogen and 2 moles of oxygen are available.
- Hydrogen reaction extent = 2 mol ÷ 2 = 1.
- Oxygen reaction extent = 2 mol ÷ 1 = 2.
- Hydrogen has the smaller reaction extent, so hydrogen is the limiting reactant.
- Water produced = 1 × 2 = 2 moles.
- Oxygen used = 1 × 1 = 1 mole, leaving 1 mole of oxygen in excess.
Key chemistry concept
Limiting reactant versus excess reactant
The limiting reactant is completely consumed first and controls the theoretical product yield. The excess reactant is supplied in a greater amount than the balanced equation requires and remains after the reaction.
When both normalized reactant amounts are equal, the reactants are present in exact stoichiometric proportions. Neither reactant is left in excess under the ideal model.
Common mistakes
Limiting-reactant calculation mistakes
- Comparing masses directly instead of first converting them to moles.
- Using coefficients from an unbalanced chemical equation.
- Confusing formula subscripts with equation coefficients.
- Selecting the reactant with fewer moles without considering the mole ratio.
- Using an incorrect molar mass for a reactant or product.
- Treating theoretical yield as guaranteed laboratory yield.